种有机溶剂的极性和其他物理常数列表表格文件下载.xls
- 文档编号:4641174
- 上传时间:2023-05-03
- 格式:XLS
- 页数:35
- 大小:41KB
种有机溶剂的极性和其他物理常数列表表格文件下载.xls
《种有机溶剂的极性和其他物理常数列表表格文件下载.xls》由会员分享,可在线阅读,更多相关《种有机溶剂的极性和其他物理常数列表表格文件下载.xls(35页珍藏版)》请在冰点文库上搜索。
CRCHandbookofDataonOrganicCompounds.Vol.IandII,CRCPress,BocaRaton/Florida1985;
(2)RC.Weast(ed.):
HandbookofChemistryandPhysics,66thedition.CRCPress,BocaRaton/Florida1985/86;
(3)J.A.Riddick,W.B.Bunger,andT.K.Sakano:
OrganicSolvents.PhysicalPropertiesandMethodrofPurification.4thedition.InA.Weissberger(ed.):
TechniquesofChemistry,Vol.II,Wiley-lnterscience,NewYork1986:
(4)A.L.McClellan:
TablesofExperimentalDipoleMoments.Freeman.SanFrancisco.London1963;
(5)A.A.MaryottandE.R.Smith:
TableofDielectricConstantsofPureLiquids.NBSCircular514;
Washington1951;
(6)DeilsteinsHandbookofOrganicChemistry.Springer-Verlag,Berlin;
(7)M.Windholz(ed.):
TheMerckIndex.10thedition,Rahway/NewJersey1983.bC.ReichardtandE.Harbusch-Grnert.LiebigsAnn.Chem1983,721;
C.Laurence,P.Nicolet.M.Lucon,andC.Reichardt,Bull.SocChimFr1987,125:
ibid.1987,1001;
cf.alsoTable7-3inChapter7.cMeltingpoint.dBoilingpointat1013mbar.eRelativepermittivity(dielectricconstant)forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter(10(-30)Cm).measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium(16969cm-1)at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET(30);
cf.Eqs.(7-27)and(7-29)inSection7.4IY.MarcusandS.Glikberg,PureAppl.Chem.57.855(1985)(Methanol).kJ.F.Coetzee(ed.):
RecommendedMethodsforPurificationofSolventsandTestsforImpurities(Acetonitrile,Sulfolane.Propylenecarbonate,Dimethylsulfoxide,N,N-Dimethylformamide,Hexamethylphosphorictriamide,Pyridine,1.2-Diaminoethane,N-Methylacetamide,andN-Methylpropionamide).PergamonPress,Oxford1982.lY.Marcus,PureAppl.Chem.57,860(1985)(Ethanol)mY.Marcus,PureAppl.Chem.58,1411(1986)(1-Propanol,2-Propanol,1-Butanol).nJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1541(1986)(Nitromethane).oB.J.Barker,J.Rosenfarb,andJ.A.Caruso,Angew.Chem.91,560(1979);
Angew.Chem.,Int.Ed.Engl.18,503(1979)(DMEU,DMPU,Tetramethylurea).pM.Breant,Bull.Soc.Chim.Fr.197/,725(I-Methylpyrrolidin-2-one).qJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.58,1535(1986)(Acetone).rC.Agarni,Bull.Soc.Chim.Fr./968,1205(1,2-Dimethoxyethane).sJ.F.CoetzeeandT.-H.Chang,PureAppl.Chem.57,633(1985)(THF,1,4-Dioxane).tK.M.KadishandJ.E.Anderson,PureAppl.Chem.59,703(1987)(Benzonitrile,Dichloromethane.1,1-Dichloroethane,1,2-Dichloroethane).mp(C)nD20(g)Er(e)u(f)01.33378.35.92.551.4475111.0(20)11.2-12.61.431837.77.7-97.71.328432.665.7-3.81.4319182.412.9-7.81.447531.69(20)7.7-4.31.455823.69(20)10.0-85.11.402116.936.8-6.21.457719.710.830.61.4253(35)191.3(32)14.2-114.51.361424.555.810.51454537.727.616.71.37196.17(20)5.6-126.21.385620.455.5-15.31.540413.1(20)5.5-88.61.399317.515.8-78.21.4113.95.7-117.21.407215.196.1-1081.395917.936.0-881.377219.925.5-114.71.397116.565.525.151.4648(25)156.2-54.51.421564.9216.51.406413.715.5-28.551.381935.9411.9-751.410413.355.5-43.81.344135.9411.818.51.479346.4513.5-61.58636.71(30)5.028.451.4816(30)43.3(30)16-73.11.390420.7(19)9.4-60.41.430536.7110.8-201.438437.7812.4TableA-1.Compilationofhundredimportantorganicsolventstogetherwiththeirphysicalconstants,arrangedbydecreasingET-valuesasempiricalparameterofsolventpolarity.-92.81.365828.86(20)11.725.61.387712.475.58.21.4707(25)37.613.6-24.41.4732.213.6-94.71.358720.569.0-201.4881(25)36.1214.111.31.456812.96.3-12.751.528225.213.4-35.71.444810.376.1-86.71.378818.51(20)9.25.81.556234.78133.0-8.81.4055.785.7-76.91.390815.38(20)90.0-1.21.4493(25)23.611.7-4.81.45427.425.27.21458829618.5-921.38815.87(30)9.2-94.91.42428.935.219.61.534217.399.8-41.551.510212.917.9-98.051.36146.685.7-32.11.45116.10(20)10.3-84.71.395813.11(20)2.7-971.416410.0(18)6.1-14.851.62738.957.3-391.392317.00(20)9.4-63.51.44594.81(20)3.8-49.81.395213.1(14.5)9.3-451.42247.5-691.399917.2(20)9.1-641.40785.86.6-691.37967.25.7-83.551.37246.026.1-171.55159.937.1-461.41229.91(20)8.9-44.31.41155.7-108.41.40727.585.8-37.51.5174.334.2-431.38372.82(20)3.0-42.21.4684(15)5.424.9-122.61.42474.82(20)4.3-45.61.52485.625.4-30.81.55685.45.2-29.51.50744.22(20)4.5-31.351.624.49(20)4.7-30.41.4387.25(20)5.711.81.42242.211.5-86.41.47733.42(16)2.7-108.61.3694.5(20)4.1-10.51.45255.8(20)4.0-49.81.38463.784.026.91.5763(30)3.69(20)3.9-116.31.35244.23.85.51.50112.270.0-123.21.38053.39(26)4.4-951.49692.381.013.31.49582.27(20)0.0-95.21.39923.08(20)3.9-111.61.62752.64(20)0.0-22.814,6022.230.0-114.71.4012.42(20)2.9-701.4291-2.6-431.4812.20(20)0.0-90.61.38761.92(20)0.0-95.31.37491.880.0-129.71.35751.84(20)0.06.71.42622.02(20)0.0aThephysicalconstantsweretakenfromthefollowingreferences:
cf.alsoTable7-3inChapter7.eRelativepermittivity(dielectricconstant)forthepureliquidat25Cunlessfollowedbyanothertemperatureinparentheses.fDipolemomentinCoulombmeter(10(-30)Cm).measuredinbenzene,tetrachloromethane,1,4-dioxane.Orn-hexaneat20-30C.1Debye=3.336x10-30Cm.gRefractiveindexattheaverageD-lineofsodium(16969cm-1)at20Cunlessfollowedbyanothertemperatureinparentheses.hNormalisedET-values,derivedfromthetransitionenergyat25Cofthelong-wavelengthabsorptionofastandardpyridinium-N-phenoxidebetainedye,ET(30);
cf.Eqs.(7-27)and(7-29)
- 配套讲稿:
如PPT文件的首页显示word图标,表示该PPT已包含配套word讲稿。双击word图标可打开word文档。
- 特殊限制:
部分文档作品中含有的国旗、国徽等图片,仅作为作品整体效果示例展示,禁止商用。设计者仅对作品中独创性部分享有著作权。
- 关 键 词:
- 有机溶剂 极性 其他 物理 常数 列表